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11.
Atsuyuki Ohta Noboru ImaiShigeru Terashima Yoshiko TachibanaKen Ikehara Hajime KatayamaAtsushi Noda 《Applied Geochemistry》2010
In all, 53 elements were analyzed in 1406 coastal sea sediment samples collected from an area off Hokkaido and the Tohoku region of Japan during a nationwide marine geochemical mapping project. The spatial distribution patterns of the elemental concentrations in coastal seas along with the existing geochemical maps in terrestrial areas were used to define natural geochemical background variation and mass transport processes. The terrestrial area is covered by mafic volcanic rocks and accretionary complexes associated with ophiolite, which has small amounts of felsic volcanic rocks and granite. The spatial distribution patterns of elements enriched in mafic lithologies such as Fe (Total Fe2O3) and Sc in marine environments are influenced by adjoining terrestrial materials. The spatial distribution patterns of Cr and Ni concentrations, which are highly abundant in ultramafic rocks on land, are used to evaluate the mass transport from land to the sea and the dispersive processes caused by oceanic currents. The scale of mass transport by oceanic currents occurs up to a distance of 100–200 km from the coast along the coastal areas. The regional differences of elements rich in felsic lithologies such as K (K2O), Nb and La in marine sediments are determined mainly by the relative proportion of minerals and lithic fragments enriching felsic materials to those associated with mafic materials. The spatial distribution of elemental concentration is not always continuous between the land areas and coastal sea areas. That difference is interpreted as resulting from (1) transportation of marine sediments by oceanic currents and storm waves, (2) contribution of volcanic materials such as tephra, (3) occurrence of shell fragments and foraminifera tests and (4) distribution of relict sediments of the last glacial age and early transgression age. Contamination with Cu, Zn, Cd, As, Mo, Sn, Sb, Hg, Pb and Bi was not observed in marine environments because the study area has little anthropogenic activity. Terrestrial materials are the dominant source for these metals. The Mo, Cd, Sn, Sb, Hg, Pb and Bi are abundant in silty and clayey sediments locally because of early diagenetic processes, authigenic precipitation and organic substances associated with these elements. The spatial distribution of As concentration shows exceptions: it is concentrated in some coarse and fine sands on the shelf. The enrichment is explained by adsorption of As, sourced from a coal field, to Fe hydroxide. 相似文献
12.
Geologic Core Holder with a CFR PEEK Body for the X-ray CT-Based Numerical Analysis of Fracture Flow Under Confining Pressure 总被引：1，自引：0，他引：1
13.
The contents of oxyanionic elements (V, Se and Mo) and cationic transition metals (Mn, Fe, Co, Ni, Cu and Zn) in sediments from near-shore to deep-sea environments were measured to clarify factors regulating the distribution of these elements in marine sediments. For cationic transition metals of which contents increase from near-shore to deep-sea environments, the chemical composition of pelagic clays is modeled by a mixture of aluminosilicates having the chemical composition of average shale and Fe–Mn oxides having the chemical composition of associated manganese nodules. The content of V is fairly constant in sediments from near-shore to deep-sea areas. The mixture model of average shale and manganese nodules holds also for V, although most of the V is located in the aluminosilicate lattices. The content of Se in the near-shore sediments is higher and that in the deep-sea sediments is lower than that in average shale. The high content in the near-shore sediments is interpreted as the addition of biogenic materials to aluminosilicates with average shale composition and the low content in deep-sea sediments is explained by oxidative release of Se from aluminosilicates. The content of Mo in sediments increases from near-shore to deep-sea environments. The general distribution of Mo in marine sediments is expressed by the mixture model. An anomalously high content of Mo in a near-shore sediment is attributed to adsorption of molybdate on manganese oxides. 相似文献
14.
Hiroshi Tsuno Atsuyuki Ohta Hiroyuki Kagi Noboru Imai Hiroaki Tao Masaharu Nomura 《Geostandards and Geoanalytical Research》2006,30(1):55-62
The oxidation states of chromium in GSJ JSO-2 (artificially contaminated soil) and three other geochemical reference materials (GSJ JSO-1, JLS-1 and JMS-1) were observed using X-ray near edge structure (XANES). For comparison, other artificially contaminated soil materials (mimic-JSO-2) were prepared by adding Cr(VI) into JSO-1. Their oxidation states of chromium were determined using XANES. The chromium contents were 1118 μg g-1 for JSO-2, 1352 μg g-1 for mimic-JSO-2 and 69-113 μg g-1 for the other reference materials. Most chromium was present as hexavalent in mimic-JSO-2. No hexavalent species were detected in other samples. These results for chromium oxidation state in JSO-2 and mimic-JSO-2 obtained with XANES resembled those obtained from a chemical extraction method. The present JSO-2 has no trace of Cr(VI), although Cr(VI) was added as a major species during preparation. On the other hand, the content of Cr(VI) obtained in mimic-JSO-2 agreed with the original Cr(VI) content. A time-elapse study showed that Cr(VI) contents in mimic-JSO-2 decreased gradually to 70% of the original abundance during 240-day preservation in dry conditions. Moreover, the abundance of Cr(VI) decreased markedly to 15% after 240 days in the wet mimic-JSO-2 containing 20% m/m of water. These experiments suggested that soil humidity enhanced the reduction of Cr(VI) and that Cr(VI) was reduced even in dry conditions. Consequently, it is reasonable to infer that Cr(VI) doped into JSO-2 was completely reduced to Cr(III) during the preservation period of 5 years. The certification of the long-term stability of the chemical form in reference materials will be much more important in future. 相似文献
15.
We studied calcite and rhodochrosite from exploratory drill cores (TH‐4 and TH‐6) near the Toyoha deposit, southwestern Hokkaido, Japan, from the aspect of stable isotope geochemistry, together with measuring the homogenization temperatures of fluid inclusions. The alteration observed in the drill cores is classified into four zones: ore mineralized zone, mixed‐layer minerals zone, kaolin minerals zone, and propylitic zone. Calcite is widespread in all the zones except for the kaolin minerals zone. The occurrence of rhodochrosite is restricted in the ore mineralized zone associated with Fe, Mn‐rich chlorite and sulfides, the mineral assemblage of which is basically equivalent to that in the Toyoha veins. The measured δ18OSMOW and δ13CPDB values of calcite scatter in the relatively narrow ranges from ?2 to 5‰ and from ?9 to ?5‰, respectively; those of rhodochrosite from 3 to 9‰ and from ?9 to ?5‰, excluding some data with large deviations. The variation of the isotopic compositions with temperature and depth could be explained by a mixing process between a heated surface meteoric water (100°C δ18O =?12‰, δ13C =?10‰) and a deep high temperature water (300°C, δ18O =?5‰, δ13C =?4‰). Boiling was less effective in isotopic fractionation than that of mixing. The plots of δ18O and δ13C indicate that the carbonates precipitated from H2CO3‐dominated fluids under the conditions of pH = 6–7 and T = 200–300°C. The sequential precipitation from calcite to rhodochrosite in a vein brought about the disequilibrium isotopic fractionation between the two minerals. The hydrothermal fluids circulated during the precipitation of carbonates in TH‐4 and TH‐6 are similar in origin to the ore‐forming fluids pertaining to the formation of veins in the Toyoha deposit. 相似文献
16.
The partition of V and Mo between manganese oxides and sea water was investigated in the sea water supply system for aquaria at the Marine Science Museum, Tokai University, where both todorokite and birnessite are precipitated from aerated well sea water. The distribution coefficient of V was an order of magnitude higher than that of Mo. Assuming that the distribution coefficients can be applied to marine environments and that manganese oxides are precipitated from sea water, the calculated contents of these oxyanionic elements in manganese oxides were comparable to those in marine manganese nodules. 相似文献
17.
This paper shows an explanatory tool (a FORTRAN program linked to GIS software), called VCM (Variable Clumping Method), for
detecting statistically significant `multi-level clumps' in the distribution of points. The multi-level clumps imply a set
of clumps whose clumping radius varies from a small radius to a large radius (in spirits, VCM is similar to the K-function method). Compared with the ordinary (fixed radius) clumping method, VCM can detect overall significant clumps in
the distribution of points.
Received: 8 March 1999/Accepted: 17 September 1999 相似文献
18.
The concentration of selenium in marine ferromanganese concretions varies between 0.02 and 1.2 mg kg−1, with an average of 0.6 mg kg−1. This is about two orders of magnitude lower than previously reported. In contrast to minor cationic elements, the concentrations of selenium are relatively uniform between ferromanganese concretions of different origins, except for hydrothermal crusts. It shows the same trends of element enrichment as other oxyanionic elements. The incorporation of selenium into ferromanganese concretions is attributed to adsorption of selenate on iron and manganese oxides. 相似文献
19.
Sarata K. Sahoo Masahiro Hosoda Ganesh Prasad Hiroyuki Takahashi Atsuyuki Sorimachi Tetsuo Ishikawa Shinji Tokonami Shigeo Uchida 《Acta Geophysica》2013,61(4):876-885
The activity concentrations of 226Ra and 228Ac in weathered Japanese soils from two selected prefectures have been measured using a γ-ray spectroscopy system with high purity germanium detector. The uranium, thorium, and rare earth elements (REEs) concentrations were determined from the same soil samples using inductively coupled plasma mass spectrometry (ICP-MS). For example, granitic rocks contain higher amounts of U, Th, and light REEs compared to other igneous rocks such as basalt and andesites. Therefore, it is necessary to understand the interaction between REEs and nature of soils since soils are complex heterogeneous mixture of organic and inorganic solids, water, and gases. In this paper, we will discuss about distribution pattern of 238U and 232Th along with REEs in soil samples of weathered acid rock (granite) collected from two prefectures of Japan: Hiroshima and Miyagi. 相似文献
20.
In the real world, there are many kinds of phenomena that are represented by points on a network, such as traffic accidents
on a street network. To analyse these phenomena, the basic point pattern methods (i.e. the nearest neighbour distance method,
the quadrat method, the K-function method and the clumping method) defined on a plane (referred to as the planar basic point pattern methods) are extended to the basic point pattern methods on a network (referred to as the network basic point pattern methods). However, like the planar basic point pattern methods, the network basic point pattern methods assume a uniform network
and this assumption is hard to accept when analysing actual phenomena. To overcome this limitation, this paper formulates
a transformation, called the uniform network transformation, that transforms a non-uniform network into a uniform network. This transformation provides a simple procedure for analysing
point patterns on non-uniform networks: first, a given non-uniform network is transformed into a uniform network; second,
the network basic point pattern methods (which assume a uniform network) are applied to this transformed uniform network.
No modification to the network basic point pattern methods is necessary. The paper also shows an actual application of this
transformation to traffic accidents in Chosei, Japan. 相似文献